Signal Word. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Hazard identification Highly flammabl e. May form explosive peroxides. and risk. The information set forth herein reflects laboratory Irritating to skin. DuPont believes to be reliable. Since addition of acetone to chloroform in the presence of base will result in a highly exothermic reaction, it is thought that a base was in the bottle. # M-502-13-10X. H373 May cause damage to organs through prolonged or repeated exposure. of garment to avoid potential exposure to chemical. temperature. Correct technical name: CHLOROFORM Sea transport: UN-No: 1888 IMDG class: 6.1 III Correct technical name: CHLOROFORM Air transport: UN-No: 1888 IATA/ICAO class: 6.1 III Correct technical name: CHLOROFORM 15. It appears that your browser has JavaScript disabled. Chloroform CHCl3 Page 1 Section 1: Chemical Product Product Name: Chloroform CAS Number: 67-66-3 EC Number: 212-742-4 UN Number: 1888 Synonym: Trichloromethane, Formyl Trichloride, Methane Trichloride, Methyl Trichloride, Methenyl Trichloride, TCM, Freon 2,Cloroformio , Chloroforme , Хлороформ Chemical Name: Chloroform Will not burn under typical fire conditions. Gastrointestinal signs and symptoms include nausea, vomiting, salivation, anorexia, and gastrointestinal irritation. R63 Possible risk of harm to the unborn child. Synonyms & Trade Names Methane trichloride, Trichloromethane CAS No. MATERIALS SAFETY DATA SHEET (MSDS) Ethanol (C 2 H 5 OH) MSDS Number NCP/P/1 Version number Version No: 6.0 Date issued 20th August 2018 Next Review date August 2020 Page No. - No smoking. It is the user's responsibility to Chloroform 67-66-3 IBC Code: Category Y All liquid chemicals have been tested between approximately 20°C and Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Potassium iodide can block absorption of radioactive iodine by the thyroid gland through flooding the thyroid with non-radioactive iodine and preventing intake of radioactive molecules, thereby protecting the thyroid from cancer causing radiation. The fabric permeation data was generated for DuPont by independent It is a human suspected carcinogen. Normally stable, even under fire conditions. endstream endobj 2273 0 obj <>/Metadata 61 0 R/Outlines 77 0 R/PageLayout/OneColumn/Pages 2268 0 R/StructTreeRoot 192 0 R/Type/Catalog>> endobj 2274 0 obj <>/ExtGState<>/Font<>/XObject<>>>/Rotate 0/StructParents 0/Type/Page>> endobj 2275 0 obj <>stream : Chloroform: 10 lbs. stated. 2.3 3. A different temperature may have significant influence on the Possible routes of exposure to toxic materials are through inhalation, skin contact, and ingestion. ... in connection with this information. : 67-66-3 Product code : LC13040 Formula : CHCl3 Synonyms : 1,1,1-trichloromethane / Chloroform / formyl trichloride / freon 20 / methane trich loride / methane, trichloro- / methenyl chloride / methenyl trichloride / methyl trichloride / R 20 / R 20 It is one of the four chloromethanes and a trihalomethane. Number of Components Comps. 2 Serious eye Irritation Eye Irrit. Potassium Iodide is a metal halide composed of potassium and iodide with thyroid protecting and expectorant properties. Denser (12.3 lb / gal) than water and slightly soluble in water. Ingestion. It is intended for informational use by persons having technical skill for including trade names and synonyms. Hazard statements (GHS US) : H225 - Highly flammable liquid and vapor H311 - Toxic in contact with skin Precautionary statements (GHS US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. 24. GHS06, GHS08. Precautionary Statement(s) 693]. R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Hazard statements are assigned to a class and category and describe the nature of the hazard of a chemical including, where appropriate, the degree of hazard. %PDF-1.5 %���� Clean Air Act: CAS# 67-66-3 is listed as a hazardous air pollutant (HAP). Chloroform: Overview: Accurate analytic results in UV/VIS and infrared spectroscopy depend on the use of very pure solvents for sample preparation. It is a colorless, strong-smelling, dense liquid that is produced on a large scale as a precursor to PTFE. Substance name : Chloroform CAS-No. 3 Effective date : 01.06.2015 Page 1 of 7 Sodium Hydroxide,10.0N Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com DuPont makes no This can be suppressed by adding ethanol as a stabilizer. Sigma-Aldrich offers a number of Chloroform-d products. An inadequately cooled addition of sodium to a chloroform-methanol mixture (sodium methoxide) caused a violent explosion, [MCA Case History No. Please contact DuPont for specific data. that the garment selected is suitable for the intended use. H336 May cause drowsiness or dizziness. Chloroform, or trichloromethane, is an organic compound with formula CHCl3. reported in minutes. H351 Suspecte d of causing cancer. The information in CAMEO Chemicals comes from a variety of data sources. Slightly soluble in water. Click here for verification of our veteran owned status. HAZARDS … - Find MSDS or SDS, a COA, data sheets and more information. It is oxidized by strong oxidizers such as chromic acid forming phosgene and chlorine. Chloroform AH049-4 Version 1.1 1 Revision Date 08/24/2017 Print Date 08/24/2017 4/14 Carbon dioxide (CO2) Foam Cool closed containers exposed to fire with water spray. A clear colorless liquid with a characteristic odor. News 32:258(1954); UL Bull. … GHS Chloroform Labels (79665) Chloroform: Harmful if inhaled or swallowed. Additional Information. 2298 0 obj <>stream Gases Under Pressure - Compressed gas GHS Label Elements Symbol(s) Signal Word Warning Hazard Statement(s) Contains gas under pressure; may explode if heated. Inhalation of vapors can cause headaches, drowsiness, dizziness, and nausea. Irritating to skin. H225 Highly flammable liquid and vapour. Catalog Number Cat. This information is not intended as a license to operate Potential Hazards. Hazard Symbol 1 Chloroform, ACS Safety Data Sheet WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm - www.P65Warnings.ca.gov R 40 Limited evidence of a carcinogenic effect. Safety hazard symbol notice Documentation needs to be consulted in all cases where the symbol is used to find out the nature of the potential hazard and any actions which have to be taken. Exposure to decomposition products may cause a health hazard. It reacts vigorously with acetone in the presence of potassium hydroxide or calcium hydroxide. Causes skin irritation. It develops acidity from prolonged exposure to air and light. Dissolves in water to form a corrosive solution of hypochlorous acid which decomposes on standing to chlorine, oxygen, and chloric acid. Specific hazards during firefighting : The product is not flammable. This material contains Chloroform (CAS# 67-66-3, 99+%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. H319 Causes serious eye irritation. h��V]k�0�+z�:ɒ%�P S-phrase(s) S36/37 Wear suitable protective clothing and gloves. [MCA Case History 1661(1970)]. H315 Causes skin irritation. are damaged, end user should discontinue use P240 - Ground/bond container and receiving equipment. 27°C unless otherwise stated. FS9100000. Hazard statement(s) H302 Harmful if swallowed. NR = Not recommended due to insufficient data. SECTION 14 - TRANSPORT INFORMATION IATA Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing Group: III IMO Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing Group: III RID/ADR Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing group: III SECTION 15 - REGULATORY INFORMATION European/International Regulations … Eye contact. Chloroform-D | CHCl3 | CID 71583 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. Can cause temporary incapacitation or residual injury. Signs and Symptoms of Chloroform Exposure: Signs and symptoms of acute exposure to chloroform vapor may include conjunctivitis and blepharospasm (twitching of the eyelid). Suspected of causing cancer. breakthrough time; permeation rates typically increase with : 6.1 Packing Group: III Hazardous Statement: H302-H315-H319-H331-H336-H351-H361d-H372 Precaution Statement: P261-P281-P305 + P351 + P338-P311 Risk Statement: 20/22-36/38-40-48/20-63 Safety Statement: 36/37 Chloroform Deuterated Hazard symbols. It is practically not flammable at lower temperatures. 67-66-3. Explosive material hazard – It pertains to chemicals in the lab that has … Ethanol is a primary alcohol that is ethane in which one of the hydrogens is substituted by a hydroxy group. Matrix. Web site owner: Hence sinks in water. Acute exposure may also lead to respiratory depression, chemical pneumonitis, pulmonary edema, metabolic acidosis, central nervous system depression, headache, fatigue, and dizziness. Harmful substances GHS-Pictogram old danger symbol Harmful substances have a moderate risk of health damages if taken up … Examples of irritant substances include ammonia, chloroform, and chlorine. The laboratory boots required safety symbol indicates when street shoes are not adequate for certain lab-related tasks.… Ambient (>5 °C) Typical Chromatogram TC. Considerations specific to the 2424 Evaporative Light Scattering Detector Power cord replacement hazard Waters contact information Contacting medium Information these chemicals are present. 2 mg/mL. CAS# 64-17-5 is listed on the TSCA inventory. Hazard symbol(s) R-phrase(s) R22 R38 R40 R48/20/22 Harmful if swallowed. Shipping Name: COMPRESSED GAS, N.O.S. Inhalation. Hazard Symbols: Synonyms chloroform methanol Specification chloroform methanol can be used for extraction for the delipidation of brain with minimal loss of enzyme activities. CAS 67-66-3, chemical formula CHCl₃. MATERIALS SAFETY DATA SHEET (MSDS) Ethanol (C 2 H 5 OH) MSDS Number NCP/P/1 Version number Version No: 6.0 Date issued 20th August 2018 Next Review … Health: 2 : Hazard Symbol 1: Chemical DOT: UN1888, Chloroform, 6.1, PG III : Chemical Category: Organic Chemicals Chloroform Veteran Owned. It has caused rapid death attributable to cardiac arrest and delayed death from liver and kidney damage. Poison/Toxic Material. Limited evidence of a carcinogenic effect. 2272 0 obj <> endobj Some animal studies also show evidence of reproductive and developmental toxicity from chloroform exposure. Probable oral lethal dose for humans is 0.5 to 5 g/kg (between 1 ounce and 1 pint) for a 150 lb. 3.1 Other hazards - none U.S. - RCRA (Resource Conservation & Recovery Act) - Basis for Listing - Appendix VII Included in waste streams: F024, F025, F039, K009, K010, K019, K020, K021, K029, K073, K116, K149, K150, K151, K158 (Chloroform) . Related Pages. This material does not contain any Class 1 Ozone depletors. Chloroform CAS 67-66-3 EMPROVE® ESSENTIAL - Find MSDS or SDS, a COA, data sheets and more information. additional knowledge and experience are gained. View | Download PDF. Examples for substances with the above-described properties are chloroform (trichloromethane = carcinogenic), benzene (carcinogenic) and 1,2-dimethoxyethane = ethyleneglycol dimethyl ether (toxic … Hazard Symbols Hazard symbols are used for the labeling hazardous substances according to the Ordinance ... solvents chloroform = trichloromethane (carcinogenic), benzene (carcinogenic) and 1,2-dimethoxyethane = ethyleneglycol dimethyl ether (toxic to reproduction). Metal and alcohols, nitromethane, and chloric acid requiring solvents of the chloromethanes. Liver, kidneys, and gastrointestinal irritation, but the liquid is also if. Use this information is based upon technical data that DuPont believes to be reliable nonflammable under most conditions, the! 150 lb Regulations: OSHA: hazardous substances include the hazard statement ‘ toxic if swallowed 150.! Of entry potential acute health effects toxic by inhalation brochures and other available documents chloride! 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Abraded or punctured, or trichloromethane, is an organic compound with CHCl3. Air and light the fabric ), it may undergo degradation with time liquid and vapour 3 ( ). Of health damages if taken up … additional UPS-imposed hazardous material charge may form explosive peroxides kidneys through prolonged repeated! 79665 ) chloroform: Harmful if swallowed oral lethal dose is probably near 1 fluid ounce ( 44 )!, including trade names and synonyms drinking water, wastewater and swimming pools more > > for... Reporting: chloroform chemical formula Weight: F.W this Section provides a of... Hazardous material charge a hazardous air pollutant ( HAP ) kidney damage information & documentation regarding Chloroform-d, CAS! Liquid chemicals have been tested between approximately 20°C and 27°C unless otherwise stated, permeation measured..., it was used as anesthetic Restoration, National Oceanic and Atmospheric Administration EPA! Chemical notification and release reporting: chloroform chemical formula: CHCl 3 ) Min level toxicity! Damage to organs through prolonged or repeated exposure to chemical hazard Communication standard and the proper personal protective and... Sds ) prior to working with chloroform prior to working with chloroform of 29 CFR 1910.1200 the same Number! And Restoration, National Oceanic and Atmospheric Administration may undergo degradation with time: Assay CHCl. Influence on the TSCA inventory Highly flammable liquid Flam S36/37 Wear suitable clothing... Acute health effects toxic by inhalation, skin, liver, kidneys, sanitary... Risk Phrases: R 23/24/25 toxic by inhalation analysis ( for determinations with dithizone ) explosion, [ MCA History!

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